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5.1.7 Cyclooctatetraene anion radical [a007]

The spectrum of Fig. 10 is significant, since it shows eight equivalent hydrogen. This would be a support for the flat structure of the anion while of the neutral molecule is not plane.

\begin{figure}\centerline{\psfig{figure=a007.ps,width=4.0cm}} % \end{figure}

Figure 10: EPR spectrum of the cyclooctatetraene anion radical.
\begin{figure}\centerline{\psfig{figure=a007esp.ps,width=16.0cm}} \end{figure}

[Exercise] Measure the intensities in the simulator and fill the rows corresponding to the spectrum [a007] in the Intensities Table 1 that you printed in the section 5.1.1.



Simulator

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Next: 5.2 Radicals that contain Up: 5.1 Radicals containing n Previous: 5.1.6 Cycloheptatrienyl neutral radical   Contents
Universidad Autónoma de Madrid, Departamento de Química Física Aplicada